Authors
Hans-Jürgen Butt, Ciro Semprebon, Periklis Papadopoulos, Doris Vollmer, Martin Brinkmann, Matteo Ciccotti
Publication date
2013
Journal
Soft Matter
Volume
9
Issue
2
Pages
418-428
Publisher
Royal Society of Chemistry
Description
To predict the properties of superamphiphobic layers we analyzed the wetting of a square and a hexagonal array of vertical pillars composed of spheres (radius R) partially sintered together. Apparent contact angles above 150° are obtained by pinning of a non-polar liquid surface at the underside of the top sphere resulting in a Fakir or Cassie state. Analytical equations are derived for the impalement pressure in the limiting case A0 ≫ R2, where A0 is the area of the regular unit cell containing a single pillar. The case of close pillars is investigated numerically. By balancing forces at the rim of a drop, we calculate the apparent receding contact angle. To describe drag reduction of a flowing liquid we calculate the apparent slip length. When considering pressure-induced flow through cylindrical capillaries of radius rc, significant drag reduction occurs only for thin capillaries. The mechanical stability with respect to …
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Scholar articles
HJ Butt, C Semprebon, P Papadopoulos, D Vollmer… - Soft Matter, 2013